Hydrothermally synthesized α-Ba2P2O7

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Hydro­thermally synthesized α-Ba2P2O7

Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained under hydro-thermal conditions. The structure belongs to the diphosphate A(2)P(2)O(7) series with A being an alkaline earth cation. α-Ba(2)P(2)O(7) crystallizes isotypically with α-Sr(2)P(2)O(7). All atomic sites have site symmetry m with the exception of two O atoms which reside on general positions. Both Ba(2+) cations ar...

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α-Ba2P2O7

Single crystals of α-Ba(2)P(2)O(7), dibarium diphosphate, were obtained by solid-state reaction. The ortho-rhom-bic structure is isotypic with α-Sr(2)P(2)O(7) and is the second polymorph obtained for this composition. The structure is built from two different BaO(9) polyhedra (both with m symmetry), with Ba-O distances in the ranges 2.7585 (10)-3.0850 (6) and 2.5794 (13)-2.9313 (4) Å. These pol...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810043527